How Do We Make Electricity from Gas?
Bolted under the cargo bay of each NASA space shuttle is a piece of equipment about a metre long. It is shaped like a narrow box and weighs a little over 100 kilograms. This small device is one of the most important items on board the shuttle. If it fails, NASA will call off an entire mission, bringing the crew back to Earth. The function of this device – small enough to fit on your desktop – is power generation. Known as a fuel cell, it efficiently produces enough electricity to run all the equipment on the spacecraft, including the crucial life support systems.
Educational Aim The aim of this lesson is to describe the key components of fuel cell systems and the process that fuel cell systems use to generate electricity from gas without combustion. Key Words for Searching Online Fuel cell systems, fuel cells, fuel cell stack, hydrogen, fuel processors, fuel reformers, electrolysis cells, alkaline fuel cell, proton exchange membrane fuel cell, polymer electrolyte membrane fuel cell, direct alcohol fuel cell, direct methanol fuel cell, direct ethanol fuel cell, phosphoric acid fuel cell, molten carbonate fuel cell, solid oxide fuel cell.
Key Learning Points
1. Fuel cells, like batteries, transform chemical energy into electricity. However, unlike batteries, fuels cells don't store electrical energy. Rather, they convert energy from gases using chemical reactions directly into electrical energy without combustion.
2. Mr William Grove produced the first fuel cell in 1839, over 150 years ago. He based his experiment on the fact that sending an electric current through water splits the water into its component parts of hydrogen and oxygen. Grove tried reversing the reaction – combining hydrogen and oxygen to produce electricity and water, which is the basis of a simple fuel cell.
3. Fuel cells are generally comprised of three main components: 1) input gases – a fuel and an oxidant;) a fuel processor; and a fuel cell.
4. Input gases – the fuel: Most fuel cells use hydrogen as a fuel. Hydrogen makes up 90 percent of the universe and is the third most abundant element on the Earth's surface. Other types of fuel cells use alcohols such as methanol or ethanol as a fuel.
Prepared by The Natural Edge Project 2008 Page 4 of 14
5. Input gases – the oxidant: Most fuel cells use oxygen as an ‘oxidant’, taken from the surrounding air. Oxygen makes up 21 percent of the volume of air and 89 percent of the mass of water.
6. Fuel processor: This is a device used to create hydrogen gas, because the gas is usually bound with other atoms in the form of a molecule. The two main fuel processing technologies for fuel cell systems are ‘fuel reformers’ and, less commonly, ‘electrolysis cells’:
1. Fuel reformers3
2. Electrolysis cells are devices that convert hydrogen-rich fuels into hydrogen gas and carbon compounds – mainly carbon dioxide gas. Fuel reformers also filter out impurities, which reduce the fuel cell’s efficiency and life expectancy. Steam reformers use heat, pressure and a catalyst.
7. Fuels and oxidants are used in fuel cells to generate electricity as direct current (DC) via a particular type of electrochemical process called an ‘oxidation-reduction’ reaction. are devices that convert water into hydrogen gas and oxygen gas using a process called electrolysis. Electrolysis is the reverse of the process that fuel cells use. There is a new type of electrolysis technology in development that uses about one tenth of the energy used by conventional electrolysis. The new technology uses naturally-occurring bacteria in an electrolysis cell to convert almost any biodegradable, organic materials into hydrogen, pure water and heat.
8. A fuel cell is comprised of two thin, porous electrodes separated by an electrolyte. The electrodes, which incorporate a catalyst, are also connected by an external electric circuit. In a typical fuel cell, hydrogen fuel or hydrogen-rich fuel and oxygen oxidant are combined to generate electricity, heat and pure water vapour. A single fuel cell produces too little electrical power to be of much use, so up to hundreds of fuel cells are linked together in series to form a fuel cell stack.
9. In a typical fuel cell, hydrogen fuel or hydrogen-rich fuel and oxygen oxidant are combined in the presence of a catalyst to generate electricity, heat and pure water vapour via a particular type of electrochemical process called an oxidation-reduction reaction. An oxidation-reduction reaction involves an oxidation half-reaction at the anode and reaction half-reaction at the cathode, and the specific half-reactions vary between the types of fuel cells.
10. Six main types of fuel cells have been developed, with the primary difference between them being the type of electrolyte used. The main differences are that in PEMFCs, DAFCs and PAFCs, positive hydrogen ions flow through the electrolyte, whereas in the AFCs, MCFCs and SOFCs, negative oxygen ions or oxygen-containing ions flow through the electrolyte.
11. Fuel cells are used in a wide variety of applications from powering buildings to cars, buses and space travel. For more information on applications, see the Australian Academy of Science website: http://www.science.org.au/nova/023/023key.htm.
Brief Background Information
Fuel Cell Systems Fuel cells are devices that convert gases into electricity without combustion. They generally comprise of three main components.
1. Input gases: a fuel and an oxidant
2. A fuel processor
3. A fuel cell stack
Input gases Hydrogen Most fuel cells use Hydrogen (annotated as ‘H’ in chemistry) as a fuel. A Hydrogen atom consists of one proton, one electron and one neutron. The stable hydrogen molecule at room temperature and atmospheric pressure is hydrogen gas, which consists of two hydrogen atoms as shown in Figure 8.1. Hydrogen makes up 90 percent of the universe and is the third most abundant element on the Earth's surface. However, it is usually bound with other atoms in a molecule so fuel processing is usually required.
Alcohol One type of fuel cell, direct alcohol fuel cells, uses alcohols such as methanol or ethanol as a fuel. Storing a liquid, such as an alcohol, is easier than storing a gas, such as hydrogen. Oxygen Most fuel cells use oxygen (O) as an oxidant. An oxygen atom consists of eight protons, eight electrons and eight neutrons. The stable oxygen molecule at room temperature and atmospheric pressure is oxygen gas, which consists of two oxygen atoms, as shown in Figure 8.2. Oxygen makes up 21 percent of the volume of air and 89 percent of the mass of water. Oxygen used in fuel cells is usually taken from the surrounding air.
Fuel Processors
Fuel processors are devices that are used to create hydrogen gas, which is usually bound with other atoms in a molecule. The two main fuel processing technologies for fuel cell systems are ‘fuel reformers’ and, less commonly, ‘electrolysis cells’.
Fuel Reformers
Fuel reformers5 are devices that convert hydrogen-rich fuels into hydrogen gas and carbon compounds – mainly carbon dioxide gas. Currently, the most commonly reformed fuel for fuel cells is called natural gas, which is mostly methane.6
5 See FuelCellWorks - Just the Basics on How Fuel Cells Work at Other hydrogen-rich fuels that are reformed include methanol, propane,
Prepared by The Natural Edge Project 2008 Page 7 of 14
butane, gasoline, diesel, solid carbon and gasified coal.7
In fuel reformers, of which there are several types, the chemical potential energy in the output hydrogen gas is about 65 percent of chemical potential energy in the input fuels. Fuel reformers also filter out impurities. Impurities can bind with a fuel cell’s catalyst, a process called poisoning, which reduces the fuel cell’s efficiency and life expectancy.
1. Natural gas (mostly methane (CH4)) reformers. This lesson discusses steam reformers, of which there are two main types:
2. Methanol (CH3OH) reformers.Fuel cells that operate at high temperature, such as molten carbonate fuel cells and solid oxide fuel cells, usually reform fuels internally and so do not require an external fuel reformer. Also, direct alcohol fuel cells use alcohols such as methanol or ethanol as a fuel and so do not require the fuel to be reformed either. Electrolysis Cells California Energy Commission (2003) Distributed Energy Resource Guide: Fuel Cells, State of California Government, USA. Available at are devices that convert water into hydrogen gas and oxygen gas using a process called electrolysis. Electrolysis is the reverse of the process that fuel cells use. InPrepared by The Natural Edge Project 2008 Page 8 of 14
conventional electrolysis cells, the chemical potential energy in the resulting hydrogen gas is 50-70 percent of the electrical energy applied. Of course, there is no extra energy value in using conventionally-generated electricity to create hydrogen and then reversing the process to use that hydrogen to generate the same quantity of electricity! However, there is an application for this arrangement in regenerative fuel cells. Regenerative fuel cells are valuable when electricity is required for 24 hours per day but only available for part of the day. For example, in remote areas where only solar-generated electricity is available, electrolysis can be used to create hydrogen gas and oxygen gas during the day and a fuel cell can be used to generate electricity at night. There is a new type of electrolysis technology in development that uses about one tenth of the energy used by conventional electrolysis. The new technology uses naturally-occurring bacteria in an electrolysis cell to convert almost any biodegradable, organic materials into hydrogen, pure water and heat in the following process:
- The bacteria consume the organic material and release protons and electrons, creating up to 0.3 volts. (The bacteria do the work of a large portion of the electricity used in a conventional electrolysis cell.)
- More than 0.2 volts are applied externally, which provides enough energy for the protons and electrons to combine and form hydrogen gas molecules.
In an electrolysis cell that uses acetic acid (found in vinegar and from glucose and cellulose fermentation) as the organic material, the chemical potential energy in the output hydrogen gas is 288 percent of the input electrical energy. When considering the total input energy – both the energy in the electricity and the chemical potential energy in the acetic acid – the hydrogen gas contains 82 percent of the total input energy. In other electrolysis cells that use lactic acid, cellulose or glucose as the organic material, the output hydrogen contains 62-82 percent of the total input energy.Fuel Cell Stack
Fuels and oxidants are used in fuel cells to generate electricity as direct current (DC) via an electrochemical process, similar to that in a battery. The main difference is that in a fuel cell, the fuel and oxidant supply is external and replenished. In a battery, the fuel and oxidant supply is stored and limited.
A fuel cell is comprised of two thin, porous electrodes separated by an electrolyte. The electrodes, which incorporate a catalyst, are also connected by an external electric circuit (see Figure 8.3):11Prepared by The Natural Edge Project 2008 Page 9 of 14
- Anode (negative electrode): has channels that distribute the fuel over the catalyst evenly and conducts the electrons from the catalyst to the external electric circuit.
- Cathode (positive electrode): has channels that distribute the oxidant over the catalyst evenly and conducts the electrons from the external circuit to the catalyst.
- Electrolyte: is a solid or solution that has a voltage across it and that facilitates in the flow of positive or negative ions from one electrode to the other while blocking electrons.
- Catalyst: is usually platinum or a nickel-platinum alloy
- External electric circuit: includes a current conditioner or load and carries electrons from the anode to the cathode.Fuel cells convert 20-60 percent of the input chemical potential energy into output electrical energy. A single fuel cell produces 0.5-0.9 volts under load, which is too low to be of much use.
Research Institute for Sustainable Energy (2006) Fuel Cells, Murdoch University. Available at Up to hundreds of fuel cells are linked together in series to form a fuel cell stack, which can generate a useful amount of voltage and power. A fuel cell stack’s power output can range from 1 kilowatt to 11 megawatts. In a typical fuel cell, hydrogen fuel or hydrogen-rich fuel and oxygen oxidant are combined in the presence of a catalyst to generate electricity, heat and pure water vapour via a particular type of electrochemical process called an oxidation-reduction reaction. An oxidation-reduction reaction involves an oxidation half-reaction at the anode and reaction half-reaction at the cathode, and the specific half-reactions vary between the types of fuel cells. Six main types of fuel cells have been developed, with the primary difference between them being the type of electrolyte used :
1. Alkaline fuel cell (AFC)
2. Proton exchange membrane fuel cell or polymer electrolyte membrane fuel cell (PEMFC)
3. Direct alcohol fuel cell (DAFC),
4. Phosphoric acid fuel cell (PAFC) also known as direct methanol (DMFC) or direct ethanol (DEFC) fuel cell, depending on the fuel used
5. Molten carbonate fuel cell (MCFC)
6. Solid oxide fuel cell (SOFC)
The main differences are that in PEMFCs, DAFCs and PAFCs, positive hydrogen ions flow through the electrolyte, whereas in the AFCs, MCFCs and SOFCs, negative oxygen ions or oxygen-containing ions flow through the electrolyte and the half reactions and full reactions are given in Table 8.3. In some types of fuel cell, ions other than hydrogen ions or oxygen ions transfer across the electrolyte. For example, AFCs use hydroxyl ions (OH-) and MCFCs use carbonates (CO32-). For an animation of a PEMFC in operation, see Nice, K. and Strickland,
Bolted under the cargo bay of each NASA space shuttle is a piece of equipment about a metre long. It is shaped like a narrow box and weighs a little over 100 kilograms. This small device is one of the most important items on board the shuttle. If it fails, NASA will call off an entire mission, bringing the crew back to Earth. The function of this device – small enough to fit on your desktop – is power generation. Known as a fuel cell, it efficiently produces enough electricity to run all the equipment on the spacecraft, including the crucial life support systems.
Educational Aim The aim of this lesson is to describe the key components of fuel cell systems and the process that fuel cell systems use to generate electricity from gas without combustion. Key Words for Searching Online Fuel cell systems, fuel cells, fuel cell stack, hydrogen, fuel processors, fuel reformers, electrolysis cells, alkaline fuel cell, proton exchange membrane fuel cell, polymer electrolyte membrane fuel cell, direct alcohol fuel cell, direct methanol fuel cell, direct ethanol fuel cell, phosphoric acid fuel cell, molten carbonate fuel cell, solid oxide fuel cell.
Key Learning Points
1. Fuel cells, like batteries, transform chemical energy into electricity. However, unlike batteries, fuels cells don't store electrical energy. Rather, they convert energy from gases using chemical reactions directly into electrical energy without combustion.
2. Mr William Grove produced the first fuel cell in 1839, over 150 years ago. He based his experiment on the fact that sending an electric current through water splits the water into its component parts of hydrogen and oxygen. Grove tried reversing the reaction – combining hydrogen and oxygen to produce electricity and water, which is the basis of a simple fuel cell.
3. Fuel cells are generally comprised of three main components: 1) input gases – a fuel and an oxidant;) a fuel processor; and a fuel cell.
4. Input gases – the fuel: Most fuel cells use hydrogen as a fuel. Hydrogen makes up 90 percent of the universe and is the third most abundant element on the Earth's surface. Other types of fuel cells use alcohols such as methanol or ethanol as a fuel.
Prepared by The Natural Edge Project 2008 Page 4 of 14
5. Input gases – the oxidant: Most fuel cells use oxygen as an ‘oxidant’, taken from the surrounding air. Oxygen makes up 21 percent of the volume of air and 89 percent of the mass of water.
6. Fuel processor: This is a device used to create hydrogen gas, because the gas is usually bound with other atoms in the form of a molecule. The two main fuel processing technologies for fuel cell systems are ‘fuel reformers’ and, less commonly, ‘electrolysis cells’:
1. Fuel reformers3
2. Electrolysis cells are devices that convert hydrogen-rich fuels into hydrogen gas and carbon compounds – mainly carbon dioxide gas. Fuel reformers also filter out impurities, which reduce the fuel cell’s efficiency and life expectancy. Steam reformers use heat, pressure and a catalyst.
7. Fuels and oxidants are used in fuel cells to generate electricity as direct current (DC) via a particular type of electrochemical process called an ‘oxidation-reduction’ reaction. are devices that convert water into hydrogen gas and oxygen gas using a process called electrolysis. Electrolysis is the reverse of the process that fuel cells use. There is a new type of electrolysis technology in development that uses about one tenth of the energy used by conventional electrolysis. The new technology uses naturally-occurring bacteria in an electrolysis cell to convert almost any biodegradable, organic materials into hydrogen, pure water and heat.
8. A fuel cell is comprised of two thin, porous electrodes separated by an electrolyte. The electrodes, which incorporate a catalyst, are also connected by an external electric circuit. In a typical fuel cell, hydrogen fuel or hydrogen-rich fuel and oxygen oxidant are combined to generate electricity, heat and pure water vapour. A single fuel cell produces too little electrical power to be of much use, so up to hundreds of fuel cells are linked together in series to form a fuel cell stack.
9. In a typical fuel cell, hydrogen fuel or hydrogen-rich fuel and oxygen oxidant are combined in the presence of a catalyst to generate electricity, heat and pure water vapour via a particular type of electrochemical process called an oxidation-reduction reaction. An oxidation-reduction reaction involves an oxidation half-reaction at the anode and reaction half-reaction at the cathode, and the specific half-reactions vary between the types of fuel cells.
10. Six main types of fuel cells have been developed, with the primary difference between them being the type of electrolyte used. The main differences are that in PEMFCs, DAFCs and PAFCs, positive hydrogen ions flow through the electrolyte, whereas in the AFCs, MCFCs and SOFCs, negative oxygen ions or oxygen-containing ions flow through the electrolyte.
11. Fuel cells are used in a wide variety of applications from powering buildings to cars, buses and space travel. For more information on applications, see the Australian Academy of Science website: http://www.science.org.au/nova/023/023key.htm.
Brief Background Information
Fuel Cell Systems Fuel cells are devices that convert gases into electricity without combustion. They generally comprise of three main components.
1. Input gases: a fuel and an oxidant
2. A fuel processor
3. A fuel cell stack
Input gases Hydrogen Most fuel cells use Hydrogen (annotated as ‘H’ in chemistry) as a fuel. A Hydrogen atom consists of one proton, one electron and one neutron. The stable hydrogen molecule at room temperature and atmospheric pressure is hydrogen gas, which consists of two hydrogen atoms as shown in Figure 8.1. Hydrogen makes up 90 percent of the universe and is the third most abundant element on the Earth's surface. However, it is usually bound with other atoms in a molecule so fuel processing is usually required.
Alcohol One type of fuel cell, direct alcohol fuel cells, uses alcohols such as methanol or ethanol as a fuel. Storing a liquid, such as an alcohol, is easier than storing a gas, such as hydrogen. Oxygen Most fuel cells use oxygen (O) as an oxidant. An oxygen atom consists of eight protons, eight electrons and eight neutrons. The stable oxygen molecule at room temperature and atmospheric pressure is oxygen gas, which consists of two oxygen atoms, as shown in Figure 8.2. Oxygen makes up 21 percent of the volume of air and 89 percent of the mass of water. Oxygen used in fuel cells is usually taken from the surrounding air.
Fuel Processors
Fuel processors are devices that are used to create hydrogen gas, which is usually bound with other atoms in a molecule. The two main fuel processing technologies for fuel cell systems are ‘fuel reformers’ and, less commonly, ‘electrolysis cells’.
Fuel Reformers
Fuel reformers5 are devices that convert hydrogen-rich fuels into hydrogen gas and carbon compounds – mainly carbon dioxide gas. Currently, the most commonly reformed fuel for fuel cells is called natural gas, which is mostly methane.6
5 See FuelCellWorks - Just the Basics on How Fuel Cells Work at Other hydrogen-rich fuels that are reformed include methanol, propane,
Prepared by The Natural Edge Project 2008 Page 7 of 14
butane, gasoline, diesel, solid carbon and gasified coal.7
In fuel reformers, of which there are several types, the chemical potential energy in the output hydrogen gas is about 65 percent of chemical potential energy in the input fuels. Fuel reformers also filter out impurities. Impurities can bind with a fuel cell’s catalyst, a process called poisoning, which reduces the fuel cell’s efficiency and life expectancy.
1. Natural gas (mostly methane (CH4)) reformers. This lesson discusses steam reformers, of which there are two main types:
2. Methanol (CH3OH) reformers.Fuel cells that operate at high temperature, such as molten carbonate fuel cells and solid oxide fuel cells, usually reform fuels internally and so do not require an external fuel reformer. Also, direct alcohol fuel cells use alcohols such as methanol or ethanol as a fuel and so do not require the fuel to be reformed either. Electrolysis Cells California Energy Commission (2003) Distributed Energy Resource Guide: Fuel Cells, State of California Government, USA. Available at are devices that convert water into hydrogen gas and oxygen gas using a process called electrolysis. Electrolysis is the reverse of the process that fuel cells use. InPrepared by The Natural Edge Project 2008 Page 8 of 14
conventional electrolysis cells, the chemical potential energy in the resulting hydrogen gas is 50-70 percent of the electrical energy applied. Of course, there is no extra energy value in using conventionally-generated electricity to create hydrogen and then reversing the process to use that hydrogen to generate the same quantity of electricity! However, there is an application for this arrangement in regenerative fuel cells. Regenerative fuel cells are valuable when electricity is required for 24 hours per day but only available for part of the day. For example, in remote areas where only solar-generated electricity is available, electrolysis can be used to create hydrogen gas and oxygen gas during the day and a fuel cell can be used to generate electricity at night. There is a new type of electrolysis technology in development that uses about one tenth of the energy used by conventional electrolysis. The new technology uses naturally-occurring bacteria in an electrolysis cell to convert almost any biodegradable, organic materials into hydrogen, pure water and heat in the following process:
- The bacteria consume the organic material and release protons and electrons, creating up to 0.3 volts. (The bacteria do the work of a large portion of the electricity used in a conventional electrolysis cell.)
- More than 0.2 volts are applied externally, which provides enough energy for the protons and electrons to combine and form hydrogen gas molecules.
In an electrolysis cell that uses acetic acid (found in vinegar and from glucose and cellulose fermentation) as the organic material, the chemical potential energy in the output hydrogen gas is 288 percent of the input electrical energy. When considering the total input energy – both the energy in the electricity and the chemical potential energy in the acetic acid – the hydrogen gas contains 82 percent of the total input energy. In other electrolysis cells that use lactic acid, cellulose or glucose as the organic material, the output hydrogen contains 62-82 percent of the total input energy.Fuel Cell Stack
Fuels and oxidants are used in fuel cells to generate electricity as direct current (DC) via an electrochemical process, similar to that in a battery. The main difference is that in a fuel cell, the fuel and oxidant supply is external and replenished. In a battery, the fuel and oxidant supply is stored and limited.
A fuel cell is comprised of two thin, porous electrodes separated by an electrolyte. The electrodes, which incorporate a catalyst, are also connected by an external electric circuit (see Figure 8.3):11Prepared by The Natural Edge Project 2008 Page 9 of 14
- Anode (negative electrode): has channels that distribute the fuel over the catalyst evenly and conducts the electrons from the catalyst to the external electric circuit.
- Cathode (positive electrode): has channels that distribute the oxidant over the catalyst evenly and conducts the electrons from the external circuit to the catalyst.
- Electrolyte: is a solid or solution that has a voltage across it and that facilitates in the flow of positive or negative ions from one electrode to the other while blocking electrons.
- Catalyst: is usually platinum or a nickel-platinum alloy
- External electric circuit: includes a current conditioner or load and carries electrons from the anode to the cathode.Fuel cells convert 20-60 percent of the input chemical potential energy into output electrical energy. A single fuel cell produces 0.5-0.9 volts under load, which is too low to be of much use.
Research Institute for Sustainable Energy (2006) Fuel Cells, Murdoch University. Available at Up to hundreds of fuel cells are linked together in series to form a fuel cell stack, which can generate a useful amount of voltage and power. A fuel cell stack’s power output can range from 1 kilowatt to 11 megawatts. In a typical fuel cell, hydrogen fuel or hydrogen-rich fuel and oxygen oxidant are combined in the presence of a catalyst to generate electricity, heat and pure water vapour via a particular type of electrochemical process called an oxidation-reduction reaction. An oxidation-reduction reaction involves an oxidation half-reaction at the anode and reaction half-reaction at the cathode, and the specific half-reactions vary between the types of fuel cells. Six main types of fuel cells have been developed, with the primary difference between them being the type of electrolyte used :
1. Alkaline fuel cell (AFC)
2. Proton exchange membrane fuel cell or polymer electrolyte membrane fuel cell (PEMFC)
3. Direct alcohol fuel cell (DAFC),
4. Phosphoric acid fuel cell (PAFC) also known as direct methanol (DMFC) or direct ethanol (DEFC) fuel cell, depending on the fuel used
5. Molten carbonate fuel cell (MCFC)
6. Solid oxide fuel cell (SOFC)
The main differences are that in PEMFCs, DAFCs and PAFCs, positive hydrogen ions flow through the electrolyte, whereas in the AFCs, MCFCs and SOFCs, negative oxygen ions or oxygen-containing ions flow through the electrolyte and the half reactions and full reactions are given in Table 8.3. In some types of fuel cell, ions other than hydrogen ions or oxygen ions transfer across the electrolyte. For example, AFCs use hydroxyl ions (OH-) and MCFCs use carbonates (CO32-). For an animation of a PEMFC in operation, see Nice, K. and Strickland,